A toy junction barrier is energy per charge. Exact arithmetic here means exact results for the stated model inputs; measured inputs still carry uncertainty and significant-figure limits.

highlighted = computed this step

Built-in voltage sets an effective barrier voltage

With no applied voltage, the effective toy barrier voltage is 3 volts.

Veff=3 VV_{\mathrm{eff}}=3\ \mathrm{V}
Built-in barrierThe barrier is energy accounting, not depletion-width geometry.q=2 CV_bi=3 VV_app=0 Vpolarity=forwardV_eff=3 VE_barrier=6 J

Energy per charge gives the barrier energy

Charge 2 coulombs times 3 volts gives 6 joules.

E=qV=23=6 JE=qV=2\cdot 3=6\ \mathrm{J}
Barrier energyThe checked barrier energy is six joules.q=2 CV_bi=3 VV_app=0 Vpolarity=forwardV_eff=3 VE_barrier=6 J