The sign of a pressure echo follows impedance order. Exact arithmetic here means exact results for the stated model inputs; measured inputs still carry uncertainty and significant-figure limits.
highlighted = computed this step
Reversing the impedance order changes the sign
The interface from 6 rayl to 2 rayl gives coefficient negative 1 over 2.
R=8−4=−1/2
The reflected pressure is inverted
Incident pressure 4 pascals times negative 1 over 2 gives negative 2 pascals.