The empty boundary case has zero filled slots. Exact arithmetic here means exact results for the stated model inputs; measured inputs still carry uncertainty and significant-figure limits.
highlighted = computed this step
The slot count comes from sites times states per site
Four repeating cells with two states per cell make 8 toy slots. This cell count is distinct from the endpoint-site count.
slots=4⋅2=8
Zero electrons leaves every slot empty
With 0 electrons, the empty count is 8 and the occupancy verdict is empty.