State prices value payoffs one state at a time.
State-price definition
A state price is the price today of $1.00 paid only in one future state.
πu=1/3,πd=2/3
Positive state prices
Here the up state price is 1/3 and the down state price is 2/3. Both are positive, which is the no-arbitrage signal.
1/3>0,2/3>0
State-price value
Any payoff is priced by multiplying each state payoff by its state price. The call price is $5.00, matching replication.
V0=1/3⋅$15.00+2/3⋅$0.00=$5.00