Three exact gas states keep pV over T fixed while different variables move. Exact arithmetic here means exact results for the stated model inputs; measured inputs still carry uncertainty and significant-figure limits.

highlighted = computed this step

Wide low-pressure state sets the ratio

The first row uses pressure 2 pascals, volume 6 cubic metres, and temperature 300 kelvin.

pV/T=2 Pa6 m3/300 K=125 J/KpV/T=2\ \text{Pa}\cdot6\ \text{m}^{3}/300\ \text{K}=\tfrac{1}{25}\ \text{J/K}
Combined gas scanThe outer rows are checked piston states.6 m^32 Pa 300 Kbefore4 m^34 Pa 400 Kafter

Pressure and volume can trade at same kelvin

At the same 300 kelvin, pressure 3 pascals and volume 4 cubic metres keep the same combined ratio.

pV/T=3 Pa4 m3/300 K=125 J/KpV/T=3\ \text{Pa}\cdot4\ \text{m}^{3}/300\ \text{K}=\tfrac{1}{25}\ \text{J/K}

Higher kelvin needs a larger pressure-volume product

The third row raises kelvin and the pressure-volume product together, so the ratio still matches.

pVTpV/T2 Pa6 m3300 K125 J/K3 Pa4 m3300 K125 J/K4 Pa4 m3400 K125 J/K\begin{array}{c|c|c|c}p&V&T&pV/T\\2\ \text{Pa}&6\ \text{m}^{3}&300\ \text{K}&\tfrac{1}{25}\ \text{J/K}\\3\ \text{Pa}&4\ \text{m}^{3}&300\ \text{K}&\tfrac{1}{25}\ \text{J/K}\\4\ \text{Pa}&4\ \text{m}^{3}&400\ \text{K}&\tfrac{1}{25}\ \text{J/K}\\\end{array}
Combined gas scanThe ratio table and checked piston states agree.6 m^32 Pa 300 Kbefore4 m^34 Pa 400 Kafter