Network byte order reads the most-significant byte first. The rule matters most when the high byte is non-zero.
highlighted = computed this step
Why byte order matters
Network byte order makes a multi-byte number unambiguous. The left byte is the high byte, so it is multiplied before the right byte is added.
multiplier=256
Network byte order
The two bytes 0x003c are read left to right. The left byte is 0x00; the right byte is 0x3c.
0x003c=60
Byte arithmetic
0x00 times 256 plus 0x3c equals 60. Here the high byte is 0, so this value would fit in one byte; the ×256 is what matters once the high byte is non-zero.
0x00×256+0x3c=60
Decode it again
For 0x05dc, the high byte 0x05 times 256 plus 0xdc equals 1500. This is the classic Ethernet MTU, and here the high byte actually matters.
0x05×256+0xdc=1500
Summary
Big-endian decoding is a rule for turning ordered bytes into one integer. Byte layout only; timing/throughput is not modeled here. Timing/throughput is not modeled here — only the exact byte layout.